Isocarbostyrils. I. Electrophilic Substitution Reactions
نویسندگان
چکیده
منابع مشابه
Regioselective Electrophilic Aromatic Substitution Reactions over Reusable Zeolites
Zeolite catalysts can play an important role in the development of greener organic syntheses through their abilities to act as heterogeneous catalysts, support reagents, entrain by-products, avoid aqueous work-ups and enhance product selectivities via shape-selectivity. We have shown that zeolites under modest conditions can have advantages in para-regioselective nitration, alkylation, acylatio...
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Herein, we describe a mild and efficient two-step procedure to introduce a thiol group on aromatic substrates. First, reaction with an activated sulfoxide leads to an arylsulfonium salt intermediate. Then, two successive beta-elimination-based dealkylation reactions afford the desired arylthiols in good to excellent yields.
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Dibromination of [2.2]paracyclophane (I) led to predominantly pseudo-ortho2 (11) and pseudo-para2 (111) disubstituted compounds, and to lesser amounts of pseudo-meta (IV) and para (V) isomers. Oxidation of these dibromides gave terephthalic acids whose esters were identified by vpc, and whose structures allowed homoannular and transannular bromination to be differentiated. Tetrabromination of I...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1971
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v71-464